A few days ago at a family get-together, I gave a bottle of molybdenum to a fellow mother so she could have it on hand for any future "stomach bugs." She told me later that in the time since I had given her the bottle of molybdenum, she had an occasion to try it for a headache that over-the-counter pain medications weren't helping her with, and the molybdenum apparently resolved her headache.
Then yesterday I found out that another member of my extended family regularly suffers from migraines. She happily accepted a bottle of molybdenum from me when I told her that it helps many people with migraines. She didn't mention that she had a headache coming on, and she took some molybdenum without telling me at the time; later on before we parted for the night, she told me that she'd already taken it and her headache was lessening.
So there's two more molybdenum anecdotes in which it appears to help with migraines. Of the many women I know who have tried molybdenum for migraines, only one reports that it hasn't helped her significantly. That's a pretty decent performance by an overlooked trace micronutrient! Especially when one considers how much some migraine medications cost.
(Disclaimer: I do not prescribe the use of pharmaceutical drugs in any way. I am not a physician, and I reject out of hand any attempt to hold me liable for what boils down to a discussion of food. Any use of a molybdenum supplement should be prudent and guided by the tested tolerable upper intake levels for its usage (see http://lpi.oregonstate.edu/mic/minerals/molybdenum for those limits). Any use of an isolated molybdenum supplement during pregnancy should be under the direction of a medical professional as such supplements have apparently not been tested during pregnancy.)
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